Conversationally, i agree that ex-wife seems much more common that former wife. In writing, though, the use of former doesn't seem so rare. Here's an interesting ngram.

Former NFL player Henry Ruggs sentenced to at least 3 years in prison

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Former NFL player Henry Ruggs sentenced to at least 3 years in prison
Former NFL player Henry Ruggs sentenced to at least 3 years in prison
Henry Ruggs Sentenced to at Least 3 Years for Crash That Killed Woman
Former NFL player Henry Ruggs sentenced to at least 3 years in prison
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Henry Ruggs sentenced to 3-plus years in prison for fatal DUI crash
Ex-Las Vegas Raider Henry Ruggs sentenced to 3-plus years in prison for
Ex-Las Vegas Raider Henry Ruggs Sentenced To 3-Plus Years In Prison For
Ex-Las Vegas Raider Henry Ruggs sentenced to 3-plus years in prison for